My favorite is 100LL Avgas. (1.6 LP HP VW). Half the lead of most race gas, long shelf life and highly consistent, and typically quite a bit less expensive. What's not to like? Can be hard to buy as it's illegal to sell for street use so some FBOs interpret that (incorrectly) as only allowed to sell into airplanes.
BTW, "100" octane rating avgas is measured a bit differently but is similar to a 100 MON car gas octane. Car street and race gas is quoted as (RON+MON)/2. 100LL Avgas is probably around 105 (R+M)/2.